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鉛酸電池鉛膏中堿式硫酸鉛的變化

 
蓄電池極板固化過(guò)程鉛膏中堿式硫酸鉛的變化極板鉛膏中有兩種類(lèi)型的骨架:三堿式硫酸鉛(3BS )和四堿式硫酸鉛(4BS ) ,這主要取決于和膏溫度與固化溫度。
a . 3BS 晶體組合和膏溫度30-60 ℃ ,固化溫度30-60 ℃ 。
b . 4BS 晶體組合和膏溫度75-95 ℃ ,鉛膏組成是4BS 晶體。這種鉛膏在固化過(guò)程主要是小晶體的溶解消失,以及4BS 大晶體的逐步長(zhǎng)大與聚集.這些過(guò)程發(fā)生在80-95 ℃ 時(shí)間10-24h 或者40- 60 ℃ 時(shí)間24-48h 的固化過(guò)程。
當(dāng)鉛膏制備在50 ℃ 時(shí)主要組成是3BS 晶體相,3BS 晶體在80-95 ℃ 溫度并有飽和水蒸氣條件下24-30h 或120-180 ℃ 時(shí)間1-4h 的固化就會(huì)轉(zhuǎn)化為4BS 晶體。在這兩種情況下主要問(wèn)題是4BS 晶粒成核速率。若以相當(dāng)高速率確保4BS 晶成核,在遍及所有鉛膏體內(nèi)構(gòu)成均勻分布的4BS 晶體大小的混亂平衡。在最初鉛膏里有一定3BS 晶體的含量,同時(shí)還有斜方晶PbO 及正方晶PbO ,它們?cè)诟邷叵鹿袒,就?huì)實(shí)現(xiàn)3BS 轉(zhuǎn)為4BS , 較高的固化溫度就有較高4BS 晶體的成核速率。

Battery plate curing process of tribasic lead sulfate paste paste the change there are two types of skeleton: three basic lead sulfate ( 3BS ) and four basic lead sulfate ( 4BS ), which mainly depends on temperature and curing temperature and cream.

A. 3BS crystal combination and paste temperature of 30-60 ℃, 30-60curing temperature.

B. 4BS crystal combination and paste temperature 75-95 ℃, paste is consisted of 4BS crystal. This paste during the curing process is mainly the small crystals dissolve away, as well as the 4BS crystal to grow and aggregation. These processes occur in 80-95 ℃, time 10-24h or 40- 60 ℃, time 24-48h curing process.

When the preparation of paste at 50 ℃is mainly comprised of 3BS crystal phase, 3BS crystal in 80-95temperature and saturated water vapor conditions 24-30h or 120-180℃, time 1-4h curing can be transformed into 4BS crystal. In two of these cases is the main problem of 4BS grain nucleation rate. A fairly high rate to ensure that the 4BS crystal nucleation, throughout all paste body to form homogeneous distribution of 4BS crystal size chaos balance. In the initial paste of a certain 3BS crystal content, at the same time also orthorhombic crystal PbO PbO and affirmative, they solidified in high temperature, will achieve 3BS into 4BS, higher curing temperature had higher 4BS crystal nucleation rate.

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